• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    A process for sweetening a sour hydrocarbon fraction containing mercaptan comprises reacting mercaptans contained in the hydrocarbon fraction with an oxidizing agent by passing the hydrocarbon fraction and the oxidizing agent into contact with a bed of metal chelate mercaptan oxidation catalyst and a solid carrier material having an average particle size of less than about 110 mesh (0.142 mm).
    公开号:SU1382404A3
    申请号:SU843826170
    申请日:1984-12-10
    公开日:1988-03-15
    发明作者:Рой Фрейм Роберт
    申请人:Юоп Инк (Фирма)；
    IPC主号:
    专利说明:

    113
    The invention relates to a method for desulfurizing a hydrocarbon fraction containing sulfur and catalysts for its implementation.
    The purpose of the invention is to increase the degree of purification.
    Example 1. A known catalytic composite material containing sulfoatal phthalocyanus-cobalt and a quaternary ammonium salt on activated carbon is prepared following an impregnating solution obtained by adding 0.15 g of cobalt phthalocyanine misopulphonate and 4 g of a 50% solution in dimethylbenzylalkylammopne chloride alcohol in 150 ml of deo isolated distilled water. Approximately 100 cm of activated carbon with a particle size of 2.0 x 0.59 mm is immersed in an impregnation solution and kept in the letters until the disappearance of the blue color of the solution disappears. The resulting rasptel-ni.iii propptainate is treated by filtration, washed with water and dried in an oven for about I h at 100 ° C. A catalytic composite material (catalyst A) obtained with such an orale is subjected to a cpap} l ry test with a given catalyst. Two other known catalysts are prepared by the method described above, by impregnation, O, 1, and 0.6 g of myopathy are carried out.
    pata phtolog iyich cob. elta, respectively, 10 (1 cm - vegetable coal with a particle size of 2.0 x 0.59 mm), as a result of this procedure, maximum cobalt is produced on the final catalyst in order to achieve more catalyst P1ICOKOI1 activity. ra, 100% and 400% more content
    0
    five
    0
    five
    0
    five
    0
    the blue color of the solution will disappear. The resulting soaked vegetable carbon is separated by filtration, rinsed with water and dried in an oven.
    Catalyst A and Catalyst B contain 0.15 and 6 g of phthalocyanine cobalt, respectively, per 100 cm of vegetable coal and 2 g of dimethylbenzyl-alkyl-C, -C, j-ammonium chloride.
    A comparative experiment is to treat high-sulfur gasoline containing about 550 parts per million of mercaptan. Such gasoline flows down through 100 cm of catalyst located in a fixed bed and a vertical tubular reactor. Gasoline is fed at a rate of about 8 per hour, along with some air, sufficient to provide about a twofold increase in the stoichiometric amount of oxygen required by the oxidation of the mercaptans contained in gasoline. Neither caustic soda nor any other alkaline reagent is added to the reactor before or during the test. The gasoline to be treated is periodically analyzed for the content of mercaptan salt.
    When catalyst A is subjected to the above test without the use of an alkaline reagent, the period of time during which a product of acceptable quality is manufactured is reduced to almost zero. However, the proposed catalyst, i.e. catalyst B makes it possible to obtain a product of an acceptable quality for about 10 hours. Thus, the catalyst for the demercapta – nadium of hydrocarbons, which is
    Ltalocyanip, than catalyst A, pro., Gives high efficiency without more active demerctapization of the hydrocarbon. Dan-HTirfi catalyst; (Catalyst B) is obtained by impregnation of about 61 cm of activator (1 vegetable coal with an average particle size of 0.125 X 0.074 mm with an impregnating solution) containing 3.7 g of cobalt phthalociapine monosulfate and 2.61 g of 50% The alcohol solution of di ethyl methyl benzyl alkyl-C, j-C d ammonium chloride, and also 200 cm of water. Plant coal and the impregnation solution are held until
    50
    55
    An alkaline reagent is a significant advancement in demercaptanization.
    EXAMPLE 2 The proposed catalyst is compared with the already known catalyst by comparative testing, known as shaking testing, the results of which show the initial activity of the catalyst. In all tests, kerosene and standard samples (13.3 cm of catalyst and 100 cm of kerosene) were used as feedstock, which were shaken in
    An alkaline reagent is a significant advancement in demercaptanization.
    EXAMPLE 2 The proposed catalyst is compared with the already known catalyst by comparative testing, known as shaking testing, the results of which show the initial activity of the catalyst. In all tests, kerosene and standard samples (13.3 cm of catalyst and 100 cm of kerosene) were used as feedstock, which were shaken in
    a two-hour period. At the end of the shaking period, the residual mercaptan concentration is determined by titration. Alkali is not used. The first series of samples was prepared by impregnating activated carbon with an average particle size of 1.67 x 0.50 mm with increasing amounts of a solution of cobalt phthalocyanine (CoPc) and 2 g per 100 g of a catalyst of 50% active quaternary ammonium chloride — Maquat M (J- TC-76 (Maquat-MQ-TC-76 is a mixture of 42% n-alkyl-dimethylbenzylammonium chloride), where alkyl is
    mix,%: C
    f2
    five; with
    60; WITH
    ft
    thirty
    and C, 9 5, dissolved in methanol, amounting to 2.5 volumes of coal. The impregnation was carried out overnight, after which it was filtered, rinsed with water and dried for 2 hours in an oven at 100-200 ° C. Other series of samples are prepared in the same way as described above, but with the difference that the charcoal is crushed to particles of size in the range of 0.105 x 0.074 mm. The results are presented in the table.
    0.05 0.15 0.30
    0.74, O
    2 o

    formula
    the invention
    15
    ten
    20 25. A method for purifying mercaptans containing hydrocarbon fraction from sulfur by contacting it with air in the presence of a catalyst containing 0.15-6.0 g of cobalt phthalocyanine monosulfonate, 2 g of dimethylbenzylalkyl-C, -C-ammonium chloride per 100 cm of carrier - charcoal, characterized in that, in order to increase the degree of purification, the process is carried out in the presence of a catalyst, the carrier of which has an average particle size of 0.125 x X 0.074 mm.
    2. Catalyst for purification of mercapto-containing hydrocarbon fraction from sulfur by air oxidation, containing 0.15-6.0 g of phthalocyanine cobalt monosulfonate, 2 g of dimethylbenzyl-alkyl-C, -C, j-ammonium chloride per 100 cm of carrier - charcoal , characterized in that, in order to increase the activity of the catalyst, it contains a carrier with an average particle size of 0.125 x 0.074 mm.

    952 968 964.
    952 944
    Transparent
    Transparent
    权利要求:
    Claims (2)
    [1]
    Claim·;.
    1. A method of purifying a mercaptan-containing hydrocarbon fraction from sulfur by contacting it with air in the presence of a catalyst containing 0.15-6.0 g of cobalt phthalocyanine monosulfonate, 2 g of dimethylbenzylalkyl-C-C-ammonium chloride per, 100 cm 3 of charcoal carrier, characterized in that, in order to increase the degree of purification, the process is conducted in the presence of a catalyst, the support of which has an average particle size of 0.125 x x 0.074 mm.
    !
    [2]
    2. A catalyst for purification of sulfur from a mercaptan-containing hydrocarbon fraction by air oxidation, containing 0.15-6.0 g of cobalt phthalocyanine monosulfonate, 2 g of dimethylbenzylalkyl-C-C 1e - | ammonium chloride per 100 cm 1 of carrier - charcoal, characterized in that, in order to increase the activity of the catalyst, it contains a carrier with an average particle size of 0.125 x 0.074 mm
    The average particle size, mm The content of cobalt, g / 100 cm 3Quaternary ammonium content, g / 100 cm 3Impregnation color Residual mercaptan, wt.h / min Kerosene color after test 1.67x0.50 0.05 2 Transparent 952 Transparent 0.15 2 Transparent 9680.30 2 Light blue * 964.0.74 2 Blue * 952 0.125x0.074 0 0 Transparent 944 Transparent 0.15 2 - 893 - n - 0.75 28801,5 2869 ... !1_
    * The color indicates that part of the phthalopane goes into solution and that the catalysts are saturated with cobalt.
    类似技术:
    公开号 | 公开日 | 专利标题
    CA1333590C|1994-12-20|Catalytic composite for sweetening of sour petroleum distillate
    SU1382404A3|1988-03-15|Method and catalytic agent for purifying mercaptan-containing hydrocarbon fractions
    US4124493A|1978-11-07|Catalytic oxidation of mercaptan in petroleum distillate including alkaline reagent and substituted ammonium halide
    US4124494A|1978-11-07|Treating a petroleum distillate with a supported metal phthalocyanine and an alkanolamine hydroxide
    US4908122A|1990-03-13|Process for sweetening a sour hydrocarbon fraction
    US4127474A|1978-11-28|Treating a petroleum distillate with an alkanolamine hydroxide and a supported oxidation catalyst impregnated with polynuclear aromatic sulfonic acid
    US4120865A|1978-10-17|Metal complex and method for preparing
    US4070307A|1978-01-24|Method of catalyst manufacture
    US4913802A|1990-04-03|Process for sweetening a sour hydrocarbon fraction
    CA1241614A|1988-09-06|Catalytic oxidation of mercaptans in petroleumdistillate
    US4028269A|1977-06-07|Process for the preparation of a solid bed catalyst system
    FI62856C|1983-03-10|FOERFARANDE FOER BEHANDLING AV ETT SURT BERGOLJEDESTILLAT
    SU860680A1|1981-08-30|Method of regenerating catalyst for marcaptan conversion
    RU2603635C1|2016-11-27|Method for demercaptanisation of hydrocarbon material
    US4142964A|1979-03-06|Process for treating a sour petroleum distillate
    RU1826987C|1993-07-07|Method of purification of high-sulfur hydrocarbon fraction containing mercaptan
    US4897180A|1990-01-30|Catalytic composite and process for mercaptan sweetening
    AU632837B2|1993-01-14|Improved catalyst and process for sweetening a sour hydrocarbon stream
    US4906354A|1990-03-06|Process for improving the thermal stability of jet fuels sweetened by oxidation
    DE2908417C2|1982-03-25|Process for the treatment of acidic petroleum distillates containing mercaptan
    US4290917A|1981-09-22|Method of manufacturing a catalytic composite
    SU422165A3|1974-03-30|METHOD OF PROCESSING BOPZINOVY FRACTIONS
    US4121997A|1978-10-24|Treating a petroleum distillate with a supported metal phthalocyanine and an alkaline reagent containing alkanolamine halide
    US4243551A|1981-01-06|Catalyst for oxidizing mercaptans and mercaptide compounds and method for preparing
    US4168245A|1979-09-18|Preparation of a supported metal phthalocyanine catalyst
    同族专利:
    公开号 | 公开日
    AT33212T|1988-04-15|
    ES538045A0|1985-11-16|
    JPH0334369B2|1991-05-22|
    IN162095B|1988-03-26|
    ES8602096A1|1985-11-16|
    EP0145408A3|1985-12-18|
    NO165149C|1991-01-09|
    EP0145408B1|1988-03-30|
    AU3590784A|1985-06-06|
    EP0145408A2|1985-06-19|
    NO844737L|1985-05-30|
    NO165149B|1990-09-24|
    US4498977A|1985-02-12|
    JPS60132651A|1985-07-15|
    ZA849226B|1986-01-29|
    DE3470120D1|1988-05-05|
    CA1224771A|1987-07-28|
    AU568167B2|1987-12-17|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    US2988500A|1959-03-13|1961-06-13|Universal Oil Prod Co|Treatment of hydrocarbon distillates|
    BE598589A|1959-12-28|
    US3408287A|1966-04-20|1968-10-29|Universal Oil Prod Co|Oxidation of mercaptans|
    US4206079A|1978-02-24|1980-06-03|Uop Inc.|Catalytic composite particularly useful for the oxidation of mercaptans contained in a sour petroleum distillate|
    US4293442A|1979-08-10|1981-10-06|Uop Inc.|Catalytic composite, method of manufacture, and process for use|
    US4318825A|1979-08-15|1982-03-09|Frame Robert R|Catalytic composite, and method of manufacture|
    US4276194A|1979-10-01|1981-06-30|Uop Inc.|Catalytic composite, method of manufacture, and process for use|
    US4364843A|1979-11-28|1982-12-21|Uop Inc.|Catalytic composite, method of manufacture, and process for use|US4490246A|1983-11-18|1984-12-25|Uop Inc.|Process for sweetening petroleum fractions|
    US4574121A|1983-11-29|1986-03-04|Uop Inc.|Metal chelate mercaptan oxidation catalyst|
    US4675100A|1985-05-30|1987-06-23|Merichem Company|Treatment of sour hydrocarbon distillate|
    US4746494A|1985-05-30|1988-05-24|Merichem Company|Treatment of sour hydrocarbon distillate|
    US4753722A|1986-06-17|1988-06-28|Merichem Company|Treatment of mercaptan-containing streams utilizing nitrogen based promoters|
    US4983670A|1988-12-20|1991-01-08|Allied-Signal Inc.|Cellulose acetate bound photosensitizer for producing singlet oxygen|
    US4913802A|1989-05-08|1990-04-03|Uop|Process for sweetening a sour hydrocarbon fraction|
    US4923596A|1989-05-22|1990-05-08|Uop|Use of quaternary ammonium compounds in a liquid/liquid process for sweetening a sour hydrocarbon fraction|
    US4929340A|1989-07-31|1990-05-29|Uop|Catalyst and process for sweetening a sour hydrocarbon fraction using dipolar compounds|
    US4956324A|1989-07-31|1990-09-11|Uop|Catalyst containing dipolar compounds useful for sweetening a sour hydrocarbon fraction|
    FR2651791B1|1989-09-08|1994-05-20|Total France Cie Raffinage Distr|METHOD OF SOFTENING IN A FIXED BED OF OIL CUTS.|
    WO2011114352A2|2010-03-17|2011-09-22|Indian Oil Corporation Limited|Process for selective removal of mercaptan from aviation turbine fuel |
    法律状态:
    优先权:
    申请号 | 申请日 | 专利标题
    US06/555,910|US4498977A|1983-11-29|1983-11-29|Catalytic oxidation of mercaptan in petroleum distillate|
    [返回顶部]